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  • Summary & Details

Characteristics of Electrode Potential Behavior and Degradation under Hydrogen Starved Operation in PEFC

固体高分子形燃料電池の燃料切れ運転に起因する劣化の特性

Detailed Information

Category(J)研究論文

Translation

Category(E)Research Paper
Author(J)1) 高木 靖雄, 2) 岡田 省吾, 3) 佐藤 雄一
Author(E)1) Yasuo Takagi, 2) Shogo Okada, 3) Yuichi Sato
Affiliation(J)1) 武蔵工業大学, 2) スズキ㈱, 3) 武蔵工業大学
Abstract(J)PEFCのスタックの一部セルを燃料不足状態で運転した場合には、スタックの作動条件によっては僅か数十秒の運転によって30%もの性能劣化を生じさせる特性があることがわかった。この燃料切れ運転時には、転位によりアノードで水電解が起こりこれにより触媒担持炭素の電食により生じ、主にアノード電極が劣化する。

Translation

Abstract(E)In order to realize commercialization of fuel cell for automobile and home CHP system application, many efforts to satisfy durability target of 5,000 hours for automobile and 40,000 hours for home CHP are required including modification of major materials such as proton conductive membrane, electrode catalyst and the others. In addition, performance degradation of MEA caused by some kind of operating and weathering conditions is another issues to understand and minimize. As degradation caused by starvation of hydrogen is one of major subjects in operating conditions to be solved, characteristics of degradation and behavior of both anode and cathode potential in starved operation are clarified in this study.

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