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  • Summary & Details

Development of Plasma CVD SiOx Hard-Coating for Transparent Injection-Molded Resin

透明樹脂射出成型品向けプラズマCVDによるSiOxハードコートの開発

Detailed Information

Author(J)1) 深田 和宏
Author(E)1) Kazuhiro Fukada
Affiliation(J)1) 芝浦機械
Affiliation(E)1) Shibaura Machine
Abstract(J)プラズマCVD法によりポリカーボネート上にSiOxハードコートを形成し,シリコーンレジン層とシリカ層の積層により高硬度かつクラックフリー膜を実現した.さらにHamaker定数に基づく界面設計により,温水下でも剥離しない高耐久構造を得た.

Translation

Abstract(E)A crack-free, high-hardness SiOx hard coating was fabricated on polycarbonate substrates using plasma chemical vapor deposition (CVD). A laminated structure composed of a silicone resin adhesion layer and a silica surface layer provided both excellent adhesion and optical transparency. However, delamination occurred under hot-water immersion. To address this, interfacial stability was analyzed using the Hamaker constant derived from Lifshitz theory. Introducing a Nb₂O₅ interlayer improved the thermodynamic stability of the interface, preventing delamination even after 250 hours in 60°C water. This approach enables rational design of durable coatings for automotive applications.

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