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  • Summary & Details

Particle Design Based on the Structural and Molecular Diffusion Characteristics of TWC Aggregates with Connected Pores

連通孔付与TWC凝集体の構造・分子拡散特性に基づく粒子設計

Detailed Information

Author(J)1) 千本 隆汰, 2) 渡邉 摩理子, 3) 花村 克悟
Author(E)1) Ryuta Chimoto, 2) Mariko Watanabe, 3) Katsunori Hanamura
Affiliation(J)1) 上智大学, 2) 上智大学, 3) 科学技術振興機構
Affiliation(E)1) Sophia University, 2) Sophia University, 3) Japan Science and Technology Agency
Abstract(J)サブミクロンスケールの連通孔を有するナノスケール粒子凝集体由来の多孔質三元触媒について,拡散シミュレーションにより拡散係数を算出し,簡易多孔質モデルとして粒子層解析に適用した.流動・拡散および反応解析から,連通孔構造と粒子積層構造が反応率に与える影響を整理し,反応促進に寄与する因子を特定した.

Translation

Abstract(E)We calculated diffusion coefficients for porous ternary catalysts composed of nanoscale particle aggregates featuring submicron-scale interconnected pores using diffusion simulations. These coefficients were subsequently incorporated into a particle-layer model as a simplified representation of the porous structure. By conducting a comprehensive analysis integrating flow, diffusion, and reaction processes, we elucidated the combined effects of the interconnected pore network and particle stacking structure on the overall reaction rate.

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